Product ID:N5755, B-NICOTINAMIDE ADENINE (SUPDAT)
MSDS Date:07/01/1999
FSC:6550
NIIN:00N092572
Status Code:A
MSDS Number: CJTDM

SIGMA CHEMICAL CO

ST LOUIS, MO 63178
US

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

SIGMA CHEMICAL COMPANY

14508 ST LOUIS, MO 63178 US

Telephone: 314-771-5765

Cage: 21076

B-NICOTINAMIDE ADENINE DINUCLEOTIDE PHOSPHATE FREE ACID

CAS: 53-59-8

RTECS: UU3440000

ACETONE

CAS: 67-64-1

RTECS: AL3150000

OSHA PEL 2400 MG/M3;1000 PPM

ACGIH TLV: 1780 MG/M3;750 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. CAUSES EYE AND SKIN IRRITATION.
MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY
TRACT. EXPOSURE MAY CAUSE: DERMATIT IS. TARGET ORGAN(S): LIVER,
KIDNEYS. THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY
INVESTIGATED.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. IN CASE OF CONTACT,
IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. IF
INHALED, REMOVE T O FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED,
WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A
PHYSICIAN. WASH CONTAMIN ATED CLOTHING BEFORE REUSE.

Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND
EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL
SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP,
PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL S ITE AFTER MATERIAL PICKUP IS
COMPLETE.

Handling and Storage Precautions:IRRITANT. IRRITATING TO EYES,
RESPIRATORY SYSTEM AND SKIN. TARGET ORGAN(S): LIVER, KIDNEYS. WEAR
SUITABLE PROTECTIVE CLOTHING.
Other Precautions:DO NOT BREATHE DUST. WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MFR TRADE NAME/PART NO: DINUCLEOTIDE PHOSPHATE FREE ACID.

Solubility in Water:SOLUBLE
Appearance and Odor:SOLID.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE, CARBON DIOXIDE, AND NITROGEN OXIDES. PHOSPHOROUS
OXIDES.

Waste Disposal Methods:DISSOLE OR MIX THE MATERIAL WITH A COMBUSTBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Toxicological Information:THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN
THOROUGHLY INVESTIGATED. RTECS #: UU3440000. PYRIDINIUM,
3-CARBAMOYL-1-BETA-D-RIBOFURANOSYL-, HYDROXIDE, 5',5'-ESTER WITH
ADENOSINE 2'-(DIHYDROGEN PHOSPHATE) 5'-(TRIHYDROGEN
PYROPHOSPHATE), INNER SALT. TOX DATA: IPR-MUS LD50:3166 MG/KG.
PCJOAU 20,160,1986. ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF
CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE A CTUAL
ENTRY IN RTECS FOR COMPLETE INFORMATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA NOT YET AVAILABLE.

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.

Federal Regulatory Information:EUROPEAN INFO. IRRITANT. R 36/37/38.
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. S 26. IN CASE OF
CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER & SEEK
MED ADVICE. S 36. WEAR SUITABLE PROTECTIVE CLOTHING. S 22. DO NOT
BREATHE DUST. TLV 7 SOURCE. FOR ACETONE: ACGIH TLV-TWA: 750 PPM
(1780 MG/M3); STEL 1000 PPM (2380 MG/M3). OSHA PEL: 8H TWA 750 PPM
(1800 MG/M3); STEL 1000 PPM (2400 M G/M3). REVIEWS, STDS & REGS:
OEL=MAK. NOHS 1974: HZD A1187; NIS 2; TNF 58; NOS 2; TNE 332. NOES
1983 : HZD A1187; NIS 1; TNF 327; NOS 4; TNE 4926; TFE 3928. EPA
TSCA SECTION 8(B) CHEM INVENTORY.